Penicillins

Type
Bacteriocidal

Mechanism of Action
inhibit bacterial growth by interfering with the transpeptidation reaction of bacterial cell wall synthesis. As structural analogs of the natural D-Ala-D-Ala substrate, β-lactams covalently bind to the active site of PBPs. This inhibits the transpeptidation reaction halting peptidoglycan synthesis, and the cell die.

Mechanism of Resistance
(1) inactivation of antibiotic by β-lactamase [mc ]
(2) modification of target PBPs
(3) impaired penetration of drug to target PBPs
(4) efflux

Contraindications
History of severe allergic reactions; anaphylaxis

Unique Side Effect
Jarish Herxheimer Reaction: Febrile reaction after first injection of penicillin in spirochetal infection

PenicillinsTargetsNota Bene
Natural PCN (Pen G, Pen V)Gram-positive organisms, gram-negative cocci, and non–-lactamase producing anaerobes
PCNase resistant PCN (Oxacillin, Nafcillin)Staphylococci and streptococciNafcillin = Excreted by liver
Extended-Spectrum Penicillins (Ampicillin, Amoxicillin)Retain antibacterial spectrum of penicillin
PLUS
improved activity against gram-negative organisms and enterococcus
Ineffective against PCN resistant staph
Antipseudomonal Penicillins (Ticarcillin)See above cellHypernatremia, hypokalemia, platelet dysfx
Antipseudomonal Penicillins (Mezlocillin, Pipercillin)See above cell1. More biliary secretion
2. Susceptible to innoculum effect and slow kill rate

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